Одержання шаруватого NaMnO(2) та його інтеркалятів

Abstract

The layered hybrid structures have been obtained by intercalation of layered birnessite NaMnO2 by organic cations (protonated form of ethylenediamine and benzylamine). Birnessit NaMnO2 was obtained by solid state synthesis and identified by X-ray diffraction and chemical analysis. The process of intercalation by organic cations at different conditions (pH, time, mixing) was investigated. The succesful synthesis of hybrid organicinorganic structure of birnessite NaMnO2 and benzylamine with brutto-formula (С6H5-CH2-NH3 +)nMnO2 was carried out. The optimal synthesis conditions for single-phase product were developed.