Preparation of Bisthiourea and 5-Amino-4-benzoyl-1,2,4-triazol-3-thione Complexes of Copper (II), Nickel and Zinc and its biological evolution.

Анотація

Novel Cu(II), Ni(II) and Zn(II) complexes that have N-({2- [(allylamino)carbonothioyl]hydrazino}carbonothioyl)benzamide, 5-allylamino-4-benzoyl-2,4- dihydro-3H-1,2,4-triazole-3-thione and 3-benzoyl-6-bromo-3,5,6,7-tetrahydro[1,2,4]triazolo[1,5- a]pyrimidine-2(1H)-thione moieties have been synthesized. All complexes were prepared by same technique due to interaction of ligands and corresponding metal (molar ratio 3:1) in boiling 95% water ethanol solution during 5 minutes. All these new compounds have been characterized by elemental analysis and various spectroscopic methods (IR, 1H, 13C NMR), and particularly for Ni(L1)2 by X-ray crystal structure determination. In addition, the possibility of biological evolution of obtained compound is shown.

Опис

*Corresponding author. Tel.: +38 050 372 5325; fax: +38 03122 35091. E-mail address: [email protected] (M. Slivka). http://www.sciencedirect.com/science/article/pii/S0022328X15302382

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Text

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Стаття

ISSN

ISSN (Print): 0022-328X

Ключові слова

Transition metal complexes; Organic ligands, Bisthiourea, 1,2,4-Triazole-3-thione and [1,2,4]triazolo[1,5-a]pyrimidine; Synthesis, Computer modeling, Antimicrobial & Fungicidal activity.

Бібліографічний опис

Mikhailo Slivka*, Maksym Fizer; Sergij Sukharev, Ruslan Mariychuk, Vasil Lendel. Preparation of Bisthiourea and 5-Amino-4-benzoyl-1,2,4-triazol-3-thione Complexes of Copper (II), Nickel and Zinc and its biological evolution. // Journal of Organo-metallic Chemistry. – 2016. – V.804 (15). – P. 6-12.

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