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DC Field | Value | Language |
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dc.contributor.author | Holomb, R.M. | - |
dc.contributor.author | Xu, Wu | - |
dc.contributor.author | Markusson, H. | - |
dc.contributor.author | Johansson, P. | - |
dc.contributor.author | Jacobsson, P. | - |
dc.date.accessioned | 2015-10-22T05:59:18Z | - |
dc.date.available | 2015-10-22T05:59:18Z | - |
dc.date.issued | 2006 | - |
dc.identifier.uri | https://dspace.uzhnu.edu.ua/jspui/handle/lib/4423 | - |
dc.description.abstract | The effect of lithium ion coordination with the bis(oxalato)borate (BOB-) [B(C2O4)2]- anion in DMSO, PEG, PPG, and d-PPG has been studied in detail by IR and Raman spectroscopy. Ab initio calculations were performed to allow a consistent analysis of the experimental data. The main features observed in the IR and Raman spectra correspond to the presence of “free”, un-coordinated, BOB- anions. Only with use of d-PPG as solvent a small amount of Li+BOB- ion pairs were detected. The Raman spectra and the calculations together indicate that Li+ coordinates bidentately with two end-oxygen atoms of the BOB- anion. The identification of ion pairs can be used to reveal limitations of LiBOB based electrolytes. The results for LiBOB are compared with literature on other Li salts. | uk |
dc.language.iso | en | uk |
dc.subject | Raman spectroscopy | uk |
dc.subject | Li+BOB- ion | uk |
dc.title | Vibrational Spectroscopy and ab Initio Studies of Lithium Bis(oxalato)borate (LiBOB) in Different Solvents | uk |
dc.type | Text | uk |
dc.pubType | Стаття | uk |
Appears in Collections: | Наукові публікації кафедри інформаційних управляючих систем та технологій |
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11_PhysChemA-2006.pdf | 127.74 kB | Adobe PDF | View/Open |
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