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https://dspace.uzhnu.edu.ua/jspui/handle/lib/21261Full metadata record
| DC Field | Value | Language |
|---|---|---|
| dc.contributor.author | Korol, Nataliya | - |
| dc.contributor.author | Slivka, Mikhailo | - |
| dc.date.accessioned | 2018-10-23T06:44:29Z | - |
| dc.date.available | 2018-10-23T06:44:29Z | - |
| dc.date.issued | 2018-03-13 | - |
| dc.identifier.citation | [7789‐33‐5] BrI (MW 206.80) InChI = 1S/BrI/c1‐2 InChIKey = CBEQRNSPHCCXSH‐UHFFFAOYSA‐N (diastereoselective cyclizations of homoallylic carbonates;1 electrophilic addition to alkenes;2 α‐bromination of steroidal aldehydes and ketones;3, 4 cleavage of carbon–metal bonds5) Physical Data: mp 40 °C; bp 116 °C (dec); d 4.416 g cm3. Solubility: sol alcohol, ether, CS2, acetic acid, acetone, CH2Cl2, MeCN, DME, toluene (but with limited solubility below −80 °C); soluble in H2O, but hydrolyzes to HBr and IOH. Form Supplied in: brownish‐black crystals or very hard, black solid; widely available (usually 97–98% purity). Handling, Storage, and Precaution: corrosive solid and vapor; readily absorbed through skin and mucous membranes; use in a fume hood and wear gloves and appropriate protective clothing; air‐, moisture‐, and light‐sensitive; should be stored refrigerated (under N2) in a tightly sealed amber bottle. Forms explosive mixtures with potassium and sodium, and reacts extremely exothermically with phosphorus and tin. | uk |
| dc.identifier.uri | https://dspace.uzhnu.edu.ua/jspui/handle/lib/21261 | - |
| dc.language.iso | en | uk |
| dc.publisher | John Wiley & Sons, Ltd | uk |
| dc.title | Iodine Monobromide | uk |
| dc.type | Text | uk |
| dc.pubType | Стаття | uk |
| Appears in Collections: | Наукові публікації кафедри органічної хімії | |
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| File | Description | Size | Format | |
|---|---|---|---|---|
| [email protected] | 392.54 kB | Adobe PDF | View/Open |
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