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https://dspace.uzhnu.edu.ua/jspui/handle/lib/21261| Title: | Iodine Monobromide |
| Authors: | Korol, Nataliya Slivka, Mikhailo |
| Issue Date: | 13-Mar-2018 |
| Publisher: | John Wiley & Sons, Ltd |
| Citation: | [7789‐33‐5] BrI (MW 206.80) InChI = 1S/BrI/c1‐2 InChIKey = CBEQRNSPHCCXSH‐UHFFFAOYSA‐N (diastereoselective cyclizations of homoallylic carbonates;1 electrophilic addition to alkenes;2 α‐bromination of steroidal aldehydes and ketones;3, 4 cleavage of carbon–metal bonds5) Physical Data: mp 40 °C; bp 116 °C (dec); d 4.416 g cm3. Solubility: sol alcohol, ether, CS2, acetic acid, acetone, CH2Cl2, MeCN, DME, toluene (but with limited solubility below −80 °C); soluble in H2O, but hydrolyzes to HBr and IOH. Form Supplied in: brownish‐black crystals or very hard, black solid; widely available (usually 97–98% purity). Handling, Storage, and Precaution: corrosive solid and vapor; readily absorbed through skin and mucous membranes; use in a fume hood and wear gloves and appropriate protective clothing; air‐, moisture‐, and light‐sensitive; should be stored refrigerated (under N2) in a tightly sealed amber bottle. Forms explosive mixtures with potassium and sodium, and reacts extremely exothermically with phosphorus and tin. |
| Type: | Text |
| Publication type: | Стаття |
| URI: | https://dspace.uzhnu.edu.ua/jspui/handle/lib/21261 |
| Appears in Collections: | Наукові публікації кафедри органічної хімії |
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